Synthesis, Characterization, Biological Activity And Thermal Degradation Of (Benzyl -; P-Chlorobenzyl-)Dithiocarbamate And 1,10-Phenanthroline Mixed Ligands Complexes (Published)
A new Cobalt (II) and Cupper (II) complexes with mixed ligands including [benzyl – (dtc1) ; p-Chlorobenzyl- (dtc2)] dithiocarbamate and 1,10- phenanthroline (phen) have been prepared by reacting CoCl2.6H2O and CuSO4.5H2O with appropriate mole ratio of these ligands .These complexes have been characterized by elemental analysis ,1H NMR , infrared , electronic spectra ,X-ray diffraction(XRD) , thermal analysis and tested for anti- bacterial activity against several bacterial strains , namely staphylococcys aureus and Escherichia coli . The results suggest an octahedral structure for all the mixed ligands complexes with two nitrogen donor atoms of heterocyclic compound ( 1,10- phenanthroline) as well as sulpher of dithiocarbamate.
Keywords: Cobalt (II)-complexes., Copper (II) Complexes., Dithiocarbamate, Mixed Ligand Complexes, Phenanthroline